In 19th-century Venezuela, powerful landowner Doña Bárbara (María Félix) is a woman committed to dominating the men surrounding her. She stops at nothing to get her hands on more land, using crime and corruption to gain her hold on society. She eventually rouses the suspicions of Santos Luzardo (Julián Soler), a well-connected rancher. But things get complicated when Bárbara takes to Santos, who harbors a secret passion for Bárbara's estranged daughter, Marisela (María Elena Marqués).
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